Texas A&M University chemical engineers have discovered a 1,000% difference in the storage capacity of metal-free, water-based battery electrodes.
Chemical engineering professor Dr. Jodie Lutkenhaus and chemistry assistant professor Dr. Daniel Tabor have published their findings about lithium-free batteries in Nature Materials.
Water based or aqueous batteries are different from lithium-ion batteries that contain cobalt. The group’s goal of researching metal-free batteries stems from having better control over the domestic supply chain since cobalt and lithium are only outsourced internationally. This safer chemistry would also prevent battery fires.
Lutkenhaus explained, “There would be no battery fires anymore because it’s water-based. In the future, if materials shortages are projected, the price of lithium-ion batteries will go way up. If we have this alternative battery, we can turn to this chemistry, where the supply is much more stable because we can manufacture them here in the United States and materials to make them are here.”
Aqueous batteries consist of a cathode, electrolyte and an anode. The cathodes and anodes are polymers that can store energy, and the electrolyte is water mixed with organic salts. The electrolyte is key to ion conduction and energy storage through its interactions with the electrode.
“If an electrode swells too much during cycling, then it can’t conduct electrons very well, and you lose all the performance,” she said. “I believe that there is a 1,000% difference in energy storage capacity, depending on the electrolyte choice because of swelling effects.”
According to their article, redox-active, non-conjugated radical polymers (electrodes) are promising candidates for metal-free aqueous batteries because of the polymers’ high discharge voltage and fast redox kinetics. The reaction is complex and difficult to resolve because of the simultaneous transfer of electrons, ions and water molecules.
The researchers noted in the Nature article, “We demonstrate the nature of the redox reaction by examining aqueous electrolytes of varying chao-/kosmotropic character using electrochemical quartz crystal microbalance with dissipation monitoring at a range of timescales.”
Dr. Tabor’s research group complemented the experimental efforts with computational simulation and analysis. The simulations gave insights into the microscopic molecular-scale picture of the structure and dynamics.
“Theory and experiment often work closely together to understand these materials. One of the new things that we do computationally in this paper is that we actually charge up the electrode to multiple states of charge and see how the surroundings respond to this charging,” Tabor said.
Researchers macroscopically observed if the battery cathode was working better in the presence of certain kinds of salts through measuring exactly how much water and salt is going into the battery as it is operating.
“We did that to explain what has been observed experimentally,” he said. “Now, we would like to expand our simulations to future systems. We needed to have our theory confirmed of what are the forces that are driving that kind of injection of water and solvent.”
“With this new energy storage technology, this is a push forward to lithium-free batteries. We have a better molecular level picture of what makes some battery electrodes work better than others, and this gives us strong evidence of where to go forward in materials design,” Tabor said.
The project is being funded by the U.S. Department of Energy and the National Science Foundation through the Texas A&M Engineering Experiment Station.
Some of the horror of a lithium ion battery fire has dissipated, but not gone entirely. They still occur, often tragically, to great effect if lit off inside a building while unattended. The frequency it seems, has gone down, even as the number of batteries in use has gone up. Perhaps the single battery in a small device is getting really safe, but a pack of batteries, now much more common due to EVs and other large high power demand devices seems to be going up.
So far your humble writer hasn’t seen any study reports about lithium ion battery pack fires vs single battery installation fires. It seems that way due to news reports, battery pack fires may get more attention as the fire from a pack is going to be much larger and harder to extinguish.
However the fire events get researched, the U.S. and EU and much of the free world is at the mercy of governments who are overlording not free economies in the lithium and cobalt trade. In the current trend to politically weaponize about anything and everything it seems a bit foolish to rely on some goods in trade that could be easily weaponized to great effect.
These observations suggest the Texas A&M work could be a very important effort to the electric powered segment of the economy, which in fact is the whole economy, indeed.
By Brian Westenhaus via Newenergyandfuel.com
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